{"id":7601,"date":"2023-07-23T17:02:41","date_gmt":"2023-07-23T09:02:41","guid":{"rendered":"https:\/\/www.ztuzx.com\/?p=7601"},"modified":"2023-07-23T17:02:41","modified_gmt":"2023-07-23T09:02:41","slug":"%e9%92%9b%e5%90%88%e9%87%91%e8%a1%a8%e9%9d%a2%e7%a3%b7%e9%85%b8%e7%9b%90%e6%b6%82%e5%b1%82%e7%9a%84%e5%88%b6%e5%a4%87%e5%8f%8a%e5%9c%a8%e9%ab%98%e6%b8%a9%e7%9b%90%e6%b0%b4%e8%92%b8%e6%b0%94%e7%8e%af","status":"publish","type":"post","link":"https:\/\/www.ztuzx.com\/?p=7601","title":{"rendered":"\u949b\u5408\u91d1\u8868\u9762\u78f7\u9178\u76d0\u6d82\u5c42\u7684\u5236\u5907\u53ca\u5728\u9ad8\u6e29\u76d0\u6c34\u84b8\u6c14\u73af\u5883\u4e2d\u7684\u8150\u8680\u884c\u4e3a\u7814\u7a76"},"content":{"rendered":"<p>1 \u4e1c\u5317\u5927\u5b66 \u6c88\u9633\u6750\u6599\u79d1\u5b66\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3\u8150\u8680\u4e0e\u9632\u62a4\u7814\u7a76\u90e8 \u6c88\u9633\uff0c 110819<\/p>\n<p>2 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href='https:\/\/www.ztuzx.com\/?p=3115' title='\u7845\u6eb6\u80f6' target='_blank' rel=\"noopener\">\u7845\u6eb6\u80f6<\/a>\u662f\u4e00\u79cd\u4ee5\u7eb3\u7c73 SiO2 \u5206\u6563\u8d28\uff0c\u53bb\u79bb\u5b50\u6c34\u4e3a\u5206\u6563\u5242\u7684\u7a33\u5b9a\u80f6\u4f53\u3002\u7eb3\u7c73\u9897\u7c92\u5177\u6709\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u53cd\u5e94\u6d3b\u6027\u9ad8\u7684\u7279\u70b9\u3002\u5728 Al(H2PO4)3 \u5f15\u5165\u7845\u6eb6\u80f6\u6539\u6027\u53ef\u5b9e\u73b0 P-OH \u548c Si-OH 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alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p>1 \u5b9e\u9a8c\u65b9\u6cd5<\/p>\n<p>\u57fa\u4e8e\u4e0d\u540c\u7684\u7845\u6eb6\u80f6\u548c Al(H2PO4)3 \u8d28\u91cf\u5206\u6570\u6bd4\uff0c\u8bbe\u8ba1\u5e76\u6df7\u5408\u540e\u83b7\u5f97\u7684\u4e09\u79cd\u4e0d\u540c\u6210\u819c\u7269\u6eb6\u6db2\u5e76\u5206\u522b\u547d\u540d\u4e3a PSi1\u3001PSi2\u3001PSi3\uff0c\u5176\u7ec4\u6210\u5982\u8868 1 \u6240\u793a\u3002\u5982\u4ee5 PSi1 \u4e3a\u4f8b\uff0c\u5176\u6210\u819c\u7269\u4e3a\u57fa\u7840\u4e0e\u989c\u586b\u6599\u548c\u52a9\u5242\u7ec4\u6210\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u6599\uff0c\u5176\u540d\u4e49\u6210\u5206(\u8d28\u91cf\u5206\u6570\uff0c%)\u4e3a\uff1aAl(H2PO4)3 32\uff0cSilica sol 32\uff0cAlumina 8\uff0cQuartz 12\uff0cCuCr2O4 5\uff0cAl(Silica coated) 5\uff0cZrO2 5\uff0cFS-50 0.5\uff0cBYK-0220.5\u3002\u914d\u7f6e\u6d82\u6599\u6210\u819c\u7269\u6eb6\u6db2\u7684\u6eb6\u8d28\u4ee5\u53ca\u586b\u6599\u5747\u4e3a\u5206\u6790\u7eaf\u836f\u54c1\uff0cFS-50 \u548c BYK-022 \u4e3a\u6539\u5584\u6d82\u6599\u6d82\u8986\u6027\u80fd\u7684\u52a9\u5242\u3002\u6d82\u6599\u5236\u5907\u8fc7\u7a0b\u5982\u4e0b\uff1a\u6309\u7167\u8d28\u91cf\u767e\u5206\u6bd4\u4f9d\u6b21\u79f0\u53d6\u6210\u819c\u7269\u6eb6\u6db2\u3001\u586b\u6599\u3001\u52a9\u5242\u5e76\u52a0\u5165\u53bb\u79bb\u5b50\u6c34\u8c03\u8282\u6d82\u6599\u9ecf\u5ea6\uff0c\u901a\u8fc7 2500r\/min \u673a\u68b0\u5206\u6563 30min \u5e76\u91c7\u7528\u5faa\u73af\u6c34\u51b7\u5374\uff0c\u968f\u540e 200\u76ee\u7b5b\u7f51\u8fc7\u6ee4\u5373\u53ef\u83b7\u5f97\u6700\u7ec8\u6d82\u6599\u3002\u5b9e\u9a8c\u6240\u91c7\u7528\u7684\u5408\u91d1\u57fa\u4f53\u4e3a Ti-6Al-4V\uff0c\u5c06 Ti-6Al-4V \u91c7\u7528\u7535\u706b\u82b1\u7ebf\u5207\u5272\u7684\u65b9\u5f0f\u52a0\u5de5\u6210\u76f4\u5f84 16mm\uff0c\u539a\u5ea6\u4e3a 2mm \u5706\u7247\uff0c\u6253\u78e8\u53bb\u9664\u6c27\u5316\u76ae\u3002\u968f\u540e\u8fdb\u884c 180\u76ee\u73bb\u7483\u73e0\u55b7\u7802\uff0c\u55b7\u7802\u538b\u529b\u4e3a 0.4MPa\uff0c\u65e0\u6c34\u4e59\u9187\u8d85\u58f0\u6e05\u6d17\u5439\u5e72\u5907\u7528\u3002<\/p>\n<p>\u8868 1 \u4e09\u79cd\u6210\u819c\u7269\u6210\u5206<\/p>\n<p>Table.1 Components of three film-forming materials<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_1.jpg' alt='\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5' \/><\/p>\n<p>\u5bf9\u4e8e 3 \u79cd\u6539\u6027\u6210\u819c\u7269\u7684\u5236\u5907\uff0c\u9996\u5148\u901a\u8fc7\u5bf9\u5176\u6df7\u5408\u6eb6\u6db2 120\u2103\u6052\u6e29\u70d8\u5e72 20h \u5236\u5907\u6539\u6027\u6210\u819c\u7269\u56fa\u4f53\u3002\u4e3a\u65b9\u4fbf\u5206\u6790\u5176\u7269\u76f8\u7ed3\u6784\uff0c\u5bf9\u6210\u819c\u7269\u56fa\u4f53\u8fdb\u884c\u7403\u78e8\uff0c\u5e76\u6700\u7ec8\u83b7\u5f97\u7c89\u4f53\u3002\u6d82\u5c42\u7684\u5236\u5907\u91c7\u7528\u5e38\u6e29\u538b\u7f29\u7a7a\u6c14\u55b7\u6d82\u7684\u65b9\u6cd5\uff0c\u5177\u4f53\u4e3a\u5c06\u5236\u5907\u597d\u7684\u6d82\u6599\u88c5\u5165 W-71 \u578b\u55b7\u67aa\u4e2d\uff0c\u55b7\u6d82\u538b\u529b 0.2MPa\uff0c\u5747\u5300\u55b7\u6d82\u5728 Ti-6Al-4V \u5408\u91d1\u8868\u9762\u3002\u4e00\u9053\u55b7\u6d82\u7ed3\u675f\u540e\u9759\u7f6e 30min \u8868\u5e72\uff0c\u968f\u540e\u8fdb\u884c\u4e8c\u9053\u55b7\u6d82\u5e76\u9759\u7f6e\u8868\u5e72 2h\uff0c\u968f\u540e\u5728 50\u2103\u4e0b\u8fdb\u884c\u9f13\u98ce\u5e72\u71e5\u56fa\u5316\uff0c\u56fa\u5316\u65f6\u95f4\u4e3a 8h\uff0c\u51b7\u5374\u540e\u5373\u53ef\u5728\u57fa\u4f53\u8868\u9762\u5236\u5f97\u8be5\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u3002<\/p>\n<p>\u6539\u6027\u6210\u819c\u7269\u7c89\u4f53\u7684\u7269\u76f8\u8868\u5f81\u91c7\u7528 X \u5c04\u7ebf\u884d\u5c04\u5206\u6790\u548c\u7ea2\u5916\u5149\u8c31\u5206\u6790\u4e24\u79cd\u65b9\u6cd5\u8fdb\u884c\u3002\u7ea2\u5916\u5149\u8c31\u5206\u6790\u6d4b\u91cf\u6837\u54c1\u91c7\u7528 KBr \u538b\u7247\u6cd5\uff0c\u6210\u819c\u7269\u7c89\u4f53\u4e0e KBr \u8d28\u91cf\u6bd4\u4e3a 100:1\uff0c\u5145\u5206\u6df7\u5408\u5747\u5300\u540e\u572820MPa \u538b\u529b\u4e0b\u5236\u6210\u5706\u7247\u6837\u54c1\uff0c\u5e76\u91c7\u7528 Thermo Scientific Nicolet iS20 \u578b Fourier \u53d8\u6362\u7ea2\u5916\u5149\u8c31\u4eea\u5bf9\u6837\u54c1\u8fdb\u884c\u7ea2\u5916\u5149\u8c31\u5206\u6790\u3002<\/p>\n<p>\u9ad8\u6e29\u76d0\u6c34\u84b8\u6c14\u73af\u5883\u4ecb\u8d28\u4e2d\u7684\u8150\u8680\u5b9e\u9a8c\u5728\u81ea\u884c\u8bbe\u8ba1\u642d\u5efa\u7684\u6c34\u84b8\u6c14\u8150\u8680\u7089\u4e2d\u8fdb\u884c\uff0c\u88c5\u7f6e\u793a\u610f\u56fe\u5982\u56fe 1\u6240\u793a\u3002\u4e3a\u786e\u4fdd 650\u2103\u4e0b\u8bd5\u6837\u8868\u9762\u6c89\u79ef\u7684\u6df7\u5408\u76d0\u7194\u5316\uff0c\u5b9e\u9a8c\u6240\u9009\u7528\u7684\u9971\u548c\u76d0\u6eb6\u6db2\u4e3a 67%Na2SO4 + 33% NaCl\uff0c\u91c7\u7528\u7a7a\u6c14\u55b7\u6d82\u5728\u8bd5\u6837\u8868\u9762\u5236\u5907 2~3 mg\/cm2 \u7684\u76d0\u819c\u3002\u968f\u540e\u5c06\u55b7\u6d82\u76d0\u819c\u7684\u8bd5\u6837\u4ee5\u60ac\u6302\u7684\u65b9\u5f0f\u7f6e\u4e8e\u77f3\u82f1\u7ba1\u4e2d\uff0c\u6bcf\u9694 20h \u53d6\u51fa\u6837\u54c1\u5e76\u7528\u53bb\u79bb\u5b50\u6c34\u6e05\u6d17\u8868\u9762\u6b8b\u5b58\u76d0\u53ca\u53ef\u6eb6\u6027\u8150\u8680\u4ea7\u7269\uff0c\u7ecf\u5e72\u71e5\u540e\u79f0\u91cd\uff0c\u5171\u53d6\u6837 5 \u6b21\uff0c\u603b\u8ba1\u5b9e\u9a8c\u65f6\u957f 100h\u3002\u6bcf\u7ec4\u5b9e\u9a8c\u6709\u4e09\u4e2a\u5e73\u884c\u6837\u54c1\u5e76\u8fdb\u884c\u79f0\u91cd(\u7cbe\u5ea6 0.01 mg)\uff0c\u4ee5\u5e73\u5747\u8d28\u91cf\u53d8\u5316\u4f5c\u4e3a\u7ed3\u679c\u5e76\u8bb0\u5f55\u3002\u5728\u8150\u8680\u5b9e\u9a8c\u524d\uff0c\u7528\u6e38\u6807\u5361\u5c3a\u6d4b\u91cf\u6837\u54c1\u7684\u51e0\u4f55\u5c3a\u5bf8\uff0c\u8ba1\u7b97\u6837\u54c1\u7684\u603b\u8868\u9762\u79ef\u53ca\u5355\u4f4d\u9762\u79ef\u7684\u8d28\u91cf\u53d8\u5316\u5e76\u7ed8\u5236\u8150\u8680\u52a8\u529b\u5b66\u66f2\u7ebf\u3002\u5229\u7528 Inspect F50 \u578b\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c(SEM)\u5e76\u7ed3\u5408 X-Max \u80fd\u8c31\u4eea(EDS)\u548c X\u2032Pert Pro \u578b X \u5c04\u7ebf\u884d\u5c04\u5206\u6790(XRD)\u5bf9\u6d82\u5c42\u7684\u5fae\u89c2\u5f62\u8c8c\u53ca\u6210\u5206\u8fdb\u884c\u5206\u6790\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_2.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u88c5' \/><\/p>\n<p>\u56fe 1 \u9ad8\u6e29\u6c34\u84b8\u6c14\u8150\u8680\u5b9e\u9a8c\u88c5\u7f6e\u793a\u610f\u56fe<\/p>\n<p>Fig.1 Schematic diagram of high-temperature vapor corrosion test device<\/p>\n<p>2 \u7ed3\u679c\u4e0e\u8ba8\u8bba<\/p>\n<p>2.1 \u4e0d\u540c\u7845\u6eb6\u80f6\u542b\u91cf\u5bf9\u78f7\u9178\u76d0\u6d82\u5c42\u6210\u819c\u6027\u80fd\u7684\u5f71\u54cd<\/p>\n<p>\u56fe 2 \u4e3a\u4e09\u79cd\u6210\u819c\u7269\u7684\u7ea2\u5916\u5438\u6536\u5149\u8c31\uff0c3 \u79cd\u6210\u819c\u7269\u5177\u6709\u8f83\u4e3a\u76f8\u4f3c\u7684\u56fe\u8c31\u3002\u7ed3\u679c\u8868\u660e\u5728 469\uff0c797\uff0c979\uff0c1109\uff0c1227\uff0c1633\uff0c2400 \u548c 3432 cm-1 \u9644\u8fd1\u5747\u5177\u6709\u5438\u6536\u5cf0\u51fa\u73b0\uff0c\u8fd9\u4e9b\u5438\u6536\u5cf0\u7684\u51fa\u73b0\u4ee3\u8868\u4e86 Si\u3001O\u3001P \u539f\u5b50\u95f4\u4e0d\u540c\u5316\u5b66\u952e\u4f38\u7f29\u632f\u52a8\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_3.jpg' alt='\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5' \/><\/p>\n<p>\u56fe 2 \u4e09\u79cd\u6bd4\u4f8b\u7684\u6210\u819c\u7269\u7684\u7ea2\u5916\u5438\u6536\u5149\u8c31<\/p>\n<p>Fig.2 Infrared absorption spectra of three film-forming materials<\/p>\n<p>\u6839\u636e SiO2-P2O5-B2O3\u7cfb\u73bb\u7483\u7684\u76f8\u5173\u7814\u7a76\uff0c469 cm-1 \u9644\u8fd1\u5438\u6536\u5cf0\u4ee3\u8868\u4e86 Si-O-Si \u7ed3\u6784\u5f2f\u66f2\u9707\u52a8[14]\uff0c970-1230cm-1 \u533a\u95f4\u51fa\u73b0\u7684\u5438\u6536\u5cf0\u5219\u4ee3\u8868\u4e86\u56fa\u5316\u4ea7\u7269\u4e2d[SiO4]\uff0c[PO4]\u56db\u9762\u4f53\u7ed3\u6784\u4e2dX-O(X=Si\/P)\u952e\u7684\u975e\u5bf9\u79f0\u5f2f\u66f2\u632f\u52a8[15-17]\uff0c975\uff0c979 \u548c 1230cm-1 \u5904\u7684\u5438\u6536\u5cf0\u4ee3\u8868 Si-O-P \u7ed3\u6784\u7684\u975e\u5bf9\u79f0\u632f\u52a8[18]\uff0c2400 \u548c 3432cm-1 \u5219\u5206\u522b\u4ee3\u8868\u4e86[SiO4]\uff0c[PO4]\u95f4\u7684 Al3+\u53c2\u4e0e\u6865\u63a5\u6240\u5f15\u8d77\u7684\u7ed3\u6784\u632f\u52a8[19-21]\u3002\u901a\u8fc7\u5206\u6790\u53ef\u77e5\uff0c\u968f\u7740\u7845\u6eb6\u80f6\u6bd4\u4f8b\u7684\u964d\u4f4e\uff0c\u6240\u6709\u5438\u6536\u5cf0\u5f3a\u5ea6\u5747\u6709\u660e\u663e\u51cf\u5f31\uff0c\u5373\u7845\u6eb6\u80f6\u7684\u51cf\u5c11\u5bf9 Si-O-P \u7ed3\u6784\u5f62\u6210\u6709\u660e\u663e\u524a\u5f31\u4f5c\u7528\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_4.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_5.png' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u88c5' \/><\/p>\n<p>\u56fe 3 \u4e3a PSi3\uff0cPSi2\uff0cPSi1 \u4e09\u79cd\u6210\u819c\u7269\u6eb6\u6db2\u56fa\u5316\u540e\u6240\u5f97\u56fa\u4f53\u6750\u6599\u7684 XRD \u56fe\u8c31\u3002\u9664 PSi1\u6210\u819c\u7269\u5916\uff0c\u5176\u4f59\u4e24\u79cd\u6210\u819c\u7269\u56fa\u5316\u540e\u5747\u6709 Al(H2PO4)3 \u6676\u4f53\u7684\u6790\u51fa\u3002\u5206\u6790\u53ef\u77e5\u968f\u7740\u7845\u6eb6\u80f6\u5360\u6bd4\u7684\u63d0\u9ad8\uff0c\u6240\u5f97\u6210\u819c\u7269\u7684\u6790\u6676\u884c\u4e3a\u53d7\u5230\u6291\u5236\uff0c\u5f53\u7845\u6eb6\u80f6\u7684\u8d28\u91cf\u5206\u6570\u63d0\u9ad8\u81f3 50wt.%\u65f6\uff0c\u5373 PSi1\u6210\u819c\u7269\u5bf9\u5e94\u7684\u5316\u5b66\u6210\u5206\uff0c\u6240\u5f97\u6210\u819c\u7269\u4e3a\u5b8c\u5168\u7684\u975e\u6676\u6001\u73bb\u7483\u3002\u7814\u7a76\u8868\u660e[22, 23]\uff0cAl(H2PO4)3\u6eb6\u6db2\u5728\u6eb6\u5242\u84b8\u53d1\u56fa\u5316\u8fc7\u7a0b\u4e2d\uff0c\u503e\u5411\u4e8e\u6790\u51fa Al(H2PO4)3 \u6676\u4f53\u3002\u5bf9\u4e8e\u73bb\u7483\u6d82\u5c42\u6216\u73bb\u7483\u6001\u6750\u6599\u800c\u8a00\uff0c\u6676\u76f8\u7684\u5927\u91cf\u6790\u51fa\u4f1a\u7834\u574f\u5176\u81f4\u5bc6\u6027\uff0c\u8fdb\u800c\u5f15\u8d77\u6d82\u5c42\u4fdd\u62a4\u6027\u80fd\u4e0b\u964d\uff0c\u800c\u4e14 Al(H2PO4)3 \u6613\u6eb6\u4e8e\u6c34\uff0c\u9ad8\u6e29\u4e0b\u5176\u81ea\u8eab\u8fd8\u4f1a\u53d1\u751f\u805a\u5408\u5f62\u6210\u591a\u5b54\u78f7\u9178\u76d0\u9676\u74f7\uff0c\u7531\u6b64\uff0c\u5728\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u4e2d\u7845\u6eb6\u80f6\u7684\u6dfb\u52a0\u91cf\u9700\u8981\u8fdb\u4e00\u6b65\u7b5b\u9009\u548c\u786e\u5b9a\u3002\u672c\u7814\u7a76\u4e2d\u8bbe\u8ba1\u4e86\u4e09\u79cd PSi3\uff0cPSi2\uff0cPSi1 \u8d28\u91cf\u6bd4\u7684\u6210\u819c\u7269\uff0c\u7269\u76f8\u5206\u6790\u7ed3\u679c\u8868\u660e PSi3\uff0cPSi2 \u7ec4\u56fa\u5316\u540e\u6240\u5f62\u6210\u7684\u6750\u6599\u4ecd\u7136\u6b8b\u7559 Al(H2PO4)3\uff0c\u800c PSi1 \u7ec4\u56fa\u5316\u4ea7\u7269\u4e3a\u5b8c\u5168\u7684\u73bb\u7483\u76f8\uff0c PSi1 \u76f8\u6bd4\u4e4b\u4e0b\u66f4\u9002\u5408\u4f5c\u4e3a\u78f7\u9178\u76d0\u6d82\u5c42\u6210\u819c\u7269\uff0c\u540e\u7eed\u7684\u9ad8\u6e29\u6c34\u84b8\u6c14\u8150\u8680\u5b9e\u9a8c\u7814\u7a76\u5747\u4e3a PSi1 \u6d82\u5c42\u5f00\u5c55\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_6.jpg' alt='\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p>\u56fe 3 PSi3\uff0cPSi2\uff0cPSi1 \u6210\u819c\u7269\u7684 X \u5c04\u7ebf\u884d\u5c04\u56fe\u8c31<\/p>\n<p>Fig.3 X-ray diffraction patterns of PSi3, PSi2, PSi1 film formers<\/p>\n<p>2.2 \u5236\u5907\u6001\u78f7\u9178\u76d0\u6d82\u5c42\u7684\u76f8\u7ed3\u6784\u7279\u5f81<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_7.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5' \/><\/p>\n<p>\u56fe 5 \u5236\u5907\u6001\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684\u8868\u9762\u4e0e\u622a\u9762\u5fae\u89c2\u5f62\u8c8c\u4ee5\u53ca\u622a\u9762 EDS \u5143\u7d20\u9762\u5206\u6790<\/p>\n<p>Fig.5 Surface (a) and cross-sectional (b) morphologies of the as-prepared silica-sol modifiedphosphate coating, and EDS elemental mappings on the cross section (c)<\/p>\n<p>\u56fe 5a \u662f\u5236\u5907\u6001\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u8868\u9762\u5fae\u89c2\u5f62\u8c8c\uff0c\u5236\u5907\u6001\u6d82\u5c42\u8868\u9762\u5177\u6709\u9cde\u7247\u72b6\u7ed3\u6784\u3002\u4ece\u56fe 5b \u5236\u5907\u6001\u6d82\u5c42\u622a\u9762\u5f62\u8c8c\u53ef\u4ee5\u5f97\u77e5\u6d82\u5c42\u4e0e\u57fa\u4f53\u95f4\u7ed3\u5408\u826f\u597d\u3002\u7ed3\u5408\u56fe 5(c)\u622a\u9762 EDS \u9762\u626b\u5143\u7d20\u5206\u5e03\u7ed3\u679c\u53ef\u77e5\uff0c\u77f3\u82f1\u3001CuCr2O4\u3001ZrO2\u3001Al \u7247\u7b49\u586b\u6599\u5728\u6d82\u5c42\u4e2d\u5206\u5e03\u5747\u5300\uff0c Al \u7247\u5728\u6d82\u5c42\u56fa\u5316\u8fc7\u7a0b\u4e2d\u56e0\u6db2\u9762\u5f20\u529b\u7684\u4f5c\u7528\u6700\u7ec8\u4ee5\u5e73\u884c\u4e8e\u57fa\u4f53\u8868\u9762\u7684\u5f62\u6001\u5747\u5300\u5206\u5e03\u3002\u6d82\u5c42\u4e2d\u5747\u5300\u5206\u5e03\u7684\u9ed1\u8272\u6591\u5757\u662f P\u3001Si\u3001O \u4e09\u79cd\u5143\u7d20\u7ec4\u6210\u73bb\u7483\u76f8\u3002<\/p>\n<p>\u56fe 6 \u4e3a\u5236\u5907\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684 Ti-6Al-4V \u5408\u91d1\u6837\u54c1\u7684 X \u5c04\u7ebf\u884d\u5c04\u5206\u6790\u56fe\u3002X \u5c04\u7ebf\u884d\u5c04\u5206\u6790\u68c0\u6d4b\u5230\u7684\u7269\u76f8\u5747\u4e3a\u6d82\u6599\u5236\u5907\u8fc7\u7a0b\u4e2d\u6240\u5f15\u5165\u7684\u65e0\u673a\u586b\u6599\uff0c\u8868\u660e\u6240\u9009\u7684\u65e0\u673a\u586b\u6599\u53ef\u4ee5\u4e0e\u9178\u6027\u78f7\u9178\u76d0\u4f53\u7cfb\u7a33\u5b9a\u5171\u5b58\u3002\u7531\u4e8e\u6d82\u5c42\u4e2d\u6676\u76f8 X \u5c04\u7ebf\u884d\u5c04\u5cf0\u5f3a\u5ea6\u9ad8<strong>\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5<\/strong>\uff0c\u6210\u819c\u7269\u975e\u6676\u76f8\u5bbd\u5cf0\u5e76\u672a\u660e\u663e\u4f53\u73b0\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_8.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5' \/><\/p>\n<p>\u56fe 6 \u5236\u5907\u6001\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684 XRD \u56fe\u8c31<\/p>\n<p>Fig.6 XRD pattern of the as-prepared silica-sol modified phosphate coating<\/p>\n<p>2.3 \u9ad8\u6e29\u76d0-\u6c34\u84b8\u6c14\u73af\u5883\u4e0b\u78f7\u9178\u76d0\u6d82\u5c42\u7684\u8150\u8680\u884c\u4e3a<\/p>\n<p>\u56fe 7 \u4e3a Ti-6Al-4V \u5408\u91d1\u57fa\u4f53\u548c\u5236\u5907\u6709\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684\u5408\u91d1\u57fa\u4f53\u5728 650\u2103\u76d0\u6c34\u84b8\u6c14\u4e2d\u8150\u8680 100h \u540e\u7684\u5b8f\u89c2\u5f62\u8c8c\u3002\u5982\u56fe 7a\uff0cc \u6240\u793a\uff0c\u8150\u8680 100h \u540e Ti-6Al-4V \u5408\u91d1\u57fa\u4f53\u8868\u9762\u6210\u4e86\u5927\u91cf\u758f\u677e\u7684\u8150\u8680\u4ea7\u7269\u3002\u4e00\u822c\u8ba4\u4e3a\u5728\u7194\u76d0\u73af\u5883\u4e2d\u949b\u5408\u91d1\u7684\u6297\u8150\u8680\u80fd\u529b\u8f83\u5dee\uff0c\u5c24\u5176\u662f\u5728\u6709\u6c2f\u76d0\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\uff0c\u5f80\u5f80\u4f1a\u751f\u6210\u4ee5 TiO2 \u4e3a\u4e3b\u8981\u6210\u5206\uff0c\u7ed3\u6784\u758f\u677e\u4e0d\u5177\u6709\u4fdd\u62a4\u6027\u7684\u6c27\u5316\u819c\u3002\u968f\u7740\u8150\u8680\u5b9e\u9a8c\u7684\u8fdb\u884c\uff0c\u7194\u878d\u76d0\u8fdb\u4e00\u6b65\u8d2f\u7a7f\u758f\u677e\u819c\u5c42\u4e0e\u57fa\u4f53\u6301\u7eed\u53d1\u751f\u9ad8\u6e29\u53cd\u5e94\u3002Cl-\u5728 Ti-6Al-4V \u7684\u8150\u8680\u8fc7\u7a0b\u4e2d\u8d77\u81ea\u50ac\u5316\u4f5c\u7528\uff0c\u53cd\u5e94\u539f\u7406\u5982\u4e0b\uff1a<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_9.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5' \/><\/p>\n<p>\u5982\u56fe 7b\uff0cd \u6240\u793a\uff0c\u5236\u5907\u6709\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684\u8bd5\u6837\u5728\u8150\u8680\u540e\u76f8\u6bd4\u4e8e\u5236\u5907\u6001\u53d1\u751f\u4e86\u660e\u663e\u7684\u989c\u8272\u53d8\u5316\uff0c\u6d82\u5c42\u7531\u94f6\u767d\u8272\u8f6c\u53d8\u4e3a\u9ed1\u7070\u8272\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_10.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u88c5' \/><\/p>\n<p>\u56fe 7 \u672a\u6d82\u8986\u548c\u6d82\u8986\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684 Ti-6Al-4V \u5408\u91d1\u8bd5\u6837\u539f\u59cb\u6001\u53ca 650\u2103\u76d0-\u6c34\u84b8\u6c14\u73af\u5883\u4e2d\u8150\u8680 100h \u540e\u7684\u5b8f\u89c2\u5f62\u8c8c<\/p>\n<p>Fig.7 Macroscopic morphologies of Ti-6Al-4V alloy samples without (a, c) and with (b, d)silica-sol modified phosphate coating before (a, b) and after (c, d) exposure for 100h at 650\u2103 inthe environment of water vapor and molten salt<\/p>\n<p>\u56fe 8 \u662f\u672a\u6d82\u8986\u548c\u6d82\u8986\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684 Ti-6Al-4V \u5408\u91d1\u8bd5\u6837\u5728 650\u2103\u76d0-\u6c34\u84b8\u6c14\u73af\u5883\u4e2d\u8150\u8680 100h \u7684\u52a8\u529b\u5b66\u66f2\u7ebf\u3002\u53ef\u89c1\u5728 20h \u524d\uff0cTC4 \u5408\u91d1\u57fa\u4f53\u589e\u91cd\u5e76\u4e0d\u660e\u663e\uff0c20h \u4e4b\u540e\u5408\u91d1\u6709\u660e\u663e\u589e\u91cd\u4e14\u589e\u91cd\u5b58\u5728\u6ce2\u52a8\uff0c\u9020\u6210\u589e\u91cd\u66f2\u7ebf\u6ce2\u52a8\u662f\u56e0\u4e3a\u8150\u8680\u8fc7\u7a0b\u4e2d\u57fa\u4f53\u6c27\u5316\u589e\u91cd\u4e0e\u8150\u8680\u4ea7\u7269\u7684\u5265\u843d\u5f15\u8d77\u7684\u5931\u91cd\u8fc7\u7a0b\u540c\u65f6\u53d1\u751f\u3002\u5236\u5907\u6d82\u5c42\u7684 Ti-6Al-4V \u5408\u91d1\u5728\u524d 20h \u8150\u8680\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u8d28\u91cf\u663e\u8457\u589e\u52a0\uff0c\u589e\u91cd\u901f\u7387\u8f83\u5feb\uff0c\u8fd9\u662f\u7531\u4e8e\u521d\u671f\u5408\u91d1\u57fa\u4f53\u4ee5\u53ca\u6d82\u5c42\u4e2d Al \u7247\u7684\u5feb\u901f\u6c27\u5316\u9020\u6210\u7684\u300220h\u540e\u6837\u54c1\u589e\u91cd\u901f\u7387\u660e\u663e\u51cf\u7f13\uff0c\u7531\u4e8e Al \u7247\u6d88\u8017\u6b86\u5c3d\uff0c\u6574\u4f53\u8d28\u91cf\u589e\u52a0\u4ec5\u4f53\u73b0\u4e3a\u57fa\u4f53\u6c27\u5316\u589e\u91cd\uff0c\u7279\u522b\u662f 40h \u540e\u6837\u54c1\u8d28\u91cf\u53d8\u5316\u975e\u5e38\u5fae\u5c0f\u3002\u4ece\u52a8\u529b\u5b66\u66f2\u7ebf\u53ef\u4ee5\u770b\u5230 40h \u540e\u6d82\u5c42\u6837\u54c1\u7684\u8d28\u91cf\u53d8\u5316\u5e45\u5ea6\u57fa\u672c\u7ef4\u6301\u5728 0.05mg\/cm2 \u4ee5\u5185\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_11.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p>\u56fe 8 \u672a\u6d82\u8986\u548c\u6d82\u8986\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684 Ti-6Al-4V \u5408\u91d1\u8bd5\u6837\u5728 650\u2103\u76d0-\u6c34\u84b8\u6c14\u73af\u5883\u4e2d\u8150\u8680 100h \u7684\u52a8\u529b\u5b66\u66f2\u7ebf<\/p>\n<p>Fig.8 Kinetic curves of Ti-6Al-4V alloy specimens without and with silica-sol modified phosphatecoating during 100h corrosion at 650 \u2103 in the environment of water vapor and molten salt<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_12.jpg' alt='\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p>\u56fe 9 \u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42 650\u2103\u76d0-\u6c34\u84b8\u6c14\u73af\u5883\u8150\u8680 100h \u540e XRD \u56fe\u8c31<\/p>\n<p>Fig.9 XRD pattern of silica-sol modified phosphate coating after corrosion for 100h at 650 \u2103 inthe environment of water vapor and molten salt<\/p>\n<p>\u56fe 9 \u4e3a\u8150\u8680 100h \u540e\u7684 X \u5c04\u7ebf\u884d\u5c04\u5206\u6790\u56fe\u8c31\u3002\u76f8\u6bd4\u4e8e\u5236\u5907\u6001\uff0c\u5e76\u672a\u68c0\u6d4b\u5230 Al\uff0c\u76f8\u53cd\u68c0\u6d4b\u5230\u4e86\u8150\u8680\u4ea7\u7269 Na7Al6Si6O24S3\u3002Na7Al6Si6O24S3 \u7684\u751f\u6210\u4e0e\u6d82\u5c42\u4e2d SiO2\u5305\u8986\u7684\u7247\u72b6 Al \u7c89\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u548c Na2SO4\u53d1\u751f\u76f8\u4e92\u4f5c\u7528\u6709\u5173\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_13.jpg' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p>\u56fe 10 \u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u5728 650\u2103\u76d0-\u6c34\u84b8\u6c14\u73af\u5883\u4e2d\u8150\u8680 100h \u540e\u8868\u9762\u548c\u622a\u9762\u5fae\u89c2\u5f62\u8c8c\u53ca\u622a\u9762 EDS \u5143\u7d20\u9762\u5206\u6790<\/p>\n<p>Fig.10 Surface (a) and cross-sectional (b) morphologies of silica-sol modified phosphate coatingafter corrosion at 650\u2103 for 100h in the environment of water vapor and molten salt, and EDSelemental mappings on the cross section (c)<\/p>\n<p>\u56fe 10a\uff0cb \u4e3a\u5236\u5907\u6709\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684 Ti-6Al-4V \u5408\u91d1\u5728 650\u2103\u76d0\u6c34\u84b8\u6c14\u8150\u8680 100h \u540e\u7684\u8868\u9762\u548c\u622a\u9762\u5fae\u89c2\u5f62\u8c8c\u3002\u8150\u8680 100h \u540e\uff0c\u6d82\u5c42\u8868\u9762\u4ecd\u4fdd\u6301\u9cde\u7247\u72b6\u7ed3\u6784\uff0c\u7531\u4e8e Al \u7684 PBR&gt;1\uff0c Al \u7247\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u53d1\u751f\u5feb\u901f\u6c27\u5316\uff0c\u56e0\u6b64\u6d82\u5c42\u8868\u9762\u81f4\u5bc6\u6027\u6709\u6240\u63d0\u5347\u3002\u4ece\u5176\u622a\u9762\u5fae\u89c2\u5f62\u8c8c\u5206\u6790\u53ef\u77e5\uff0c\u5728\u6d82\u5c42\u548c\u57fa\u4f53\u4e2d\u95f4\u751f\u6210\u4e00\u5c42\u5e73\u5747\u539a\u5ea6\u7ea6\u4e3a 3\u03bcm \u7684\u6c27\u5316\u819c\uff0cEDS \u9762\u5206\u6790\u7ed3\u679c\u663e\u793a\u6c27\u5316\u819c\u6210\u5206\u4ee5 Ti\uff0cO \u4ee5\u53ca\u5c11\u91cf\u7684 Al \u4e3a\u4e3b\uff0c\u56e0\u6b64\u8be5\u6c27\u5316\u819c\u6210\u5206\u4e3a\u6c27\u5316\u819c\u6210\u5206\u5e94\u4e3a TiO2\u548c Al2O3\u3002\u56e0\u4e3a\u754c\u9762\u5904 Ti \u53d1\u751f\u5927\u91cf\u6c27\u5316\u751f\u6210\u4e86 TiO2\uff0c\u6240\u4ee5\u5728\u6c27\u5316\u819c\u4e0b\u65b9\u8fd8\u51fa\u73b0\u4e00\u5c42\u539a\u5ea6\u7ea6\u4e3a 3\u03bcm\u7684 Al \u7684\u5bcc\u96c6\u533a\uff0c\u8150\u8680\u540e\u6d82\u5c42\u4e2d\u9ed1\u8272\u6591\u5757\u72b6\u73bb\u7483\u76f8\u4ecd\u7136\u5b58\u5728\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_14.png' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_15.png' alt='\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd_\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5' \/><\/p>\n<p>\u7efc\u4e0a\u5206\u6790\uff0c\u76f8\u6bd4\u4e8e\u57fa\u4f53\uff0c\u5236\u5907\u6709\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u7684\u6837\u54c1\u5177\u6709\u826f\u597d\u7684\u8010\u8680\u6027\u80fd\uff0c\u5176\u4e3b\u8981\u539f\u56e0\u53ef\u5f52\u7ed3\u4e8e\u4e24\u4e2a\u65b9\u9762\u3002\u5373\u6d82\u5c42\u7684\u4e2d\u6210\u819c\u7269\u53ca\u586b\u6599\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u4ee5\u53ca Al \u7247\u5bf9\u7194\u878d\u76d0\u7684\u6d88\u8017\u3002\u5bf9\u4e8e\u4ee5 SiO2-P2O5\u7cfb\u73bb\u7483\u4e3a\u57fa\u4f53\uff0cAl2O3\u3001ZrO2\u3001Al\u3001SiO2\u7b49\u65e0\u673a\u7269\u4e3a\u586b\u6599\u7684\u78f7\u9178\u76d0\u6d82\u5c42\uff0c\u5728 650\u2103\u76d0\u6c34\u84b8\u6c14\u4ecb\u8d28\u4e2d\u8150\u8680\u6297\u6027\u53d6\u51b3\u4e8e\u590d\u5408\u6d82\u5c42\u5404\u7ec4\u6210\u90e8\u5206\u30022.1 \u5c0f\u8282\u4e2d\u6709\u5173\u78f7\u9178\u76d0\u6210\u819c\u7269\u6210\u5206\u8bbe\u8ba1\u7684\u7814\u7a76\u8868\u660e\uff0c\u5bf9\u4e8e PSi1 \u6539\u6027\u6210\u819c\u7269\uff0c\u5176\u6539\u6027\u540e\u56fa\u5316\u4e3b\u8981\u5f62\u6210\u4ee5[-Si-O-P-]\u4e3a\u94fe\u8282\uff0c [PO4]\u4e0e[SiO4]\u901a\u8fc7 Al3+\u6865\u63a5\u7684\u73bb\u7483\u3002\u76f8\u6bd4\u4ee5 Na+\uff0cK+\u7b49\u79bb\u5b50\u63ba\u6742\u7684\u7845\u9178\u76d0\u73bb\u7483\uff0c\u5728\u8150\u8680\u8fc7\u7a0b\u4e2d\uff0c\u7194\u878d\u76d0\u4e2d\u7684 Na+\u65e0\u6cd5\u4e0e Al3+\u7f6e\u6362\u5e76\u4ee3\u66ff Al3+\u53c2\u4e0e\u73bb\u7483\u7f51\u7edc\u5f62\u6210\uff0c\u56e0\u6b64\u65e0\u6cd5\u9020\u6210\u56e0\u79bb\u5b50\u4f53\u79ef\u548c\u7535\u8d1f\u6027\u5dee\u5f02\u4ea7\u751f\u6d82\u5c42\u5185\u7684\u62c9\u5e94\u529b\uff0c\u56fe 10c)\u7845\u6eb6\u80f6\u6539\u6027\u78f7\u9178\u76d0\u6d82\u5c42\u5728 650\u2103\u76d0\u6c34\u84b8\u6c14\u73af\u5883\u4e2d\u8150\u8680 100h \u540e EDS \u9762\u626b\u7ed3\u679c\u4e2d Na \u7684\u5206\u5e03\u60c5\u51b5\u8bc1\u5b9e\u4e86\u4ee5\u4e0a\u8bba\u8ff0\u3002<\/p>\n<p>\u5728 650\u2103\u6e29\u5ea6\u4e0b\uff0c67 wt.% Na2SO4 + 33 wt.% NaCl \u6df7\u5408\u76d0\u5904\u4e8e\u7194\u878d\u72b6\u6001\uff0c\u4f46\u8be5\u6e29\u5ea6\u8fdc\u4f4e\u4e8e Na2SO4\u7194\u70b9\uff0c\u56e0\u6b64\u5728\u6240\u5f62\u6210\u7684\u5171\u6676\u7194\u878d\u76d0\u4e2d\uff0cSO42-\u672a\u53d1\u751f\u89e3\u79bb\u5f62\u6210 S6+\u3001SO3\u3001SO2 \u7b49\u5206\u89e3\u4ea7\u7269\uff0c\u8150\u8680\u8fc7\u7a0b\u4e3b\u8981\u7531 Cl-\u4e3b\u5bfc\u3002\u5bf9\u4e8e\u6d82\u5c42\u4e2d SiO2\u3001Al2O3\u3001ZrO2 \u586b\u6599\uff0c\u5728 650\u2103\u542b\u6709 NaCl \u548c\u6c34\u84b8\u6c14\u73af\u5883\u4e2d\uff0c\u5176\u70ed\u5316\u5b66\u53cd\u5e94\u5982(4-8)\uff0c(4-9)\uff0c(4-10)\u6240\u793a\u3002<\/p>\n<p><img src='https:\/\/www.ztuzx.com\/wp-content\/uploads\/2023\/07\/1690102954334_16.jpg' alt='\u5408\u91d1\u6d82\u88c5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5_\u5408\u91d1\u6d82\u6599\u5236\u9020\u65b9\u6cd5\u6709\u54ea\u51e0\u79cd' \/><\/p>\n<p>\u4e0a\u8ff0\u4e09\u5f0f\u53cd\u5e94\u7684 \u0394G&gt;0\uff0c\u7ed3\u5408\u56fe 10b \u53ef\u77e5\u4f5c\u4e3a\u586b\u6599\u7684\u6c27\u5316\u7269\u5728 650\u2103 \u542b\u6709 NaCl \u6c34\u84b8\u6c14\u73af\u5883\u4e2d\u53ef\u7a33\u5b9a\u5b58\u5728\uff0c\u5373\u6d82\u5c42\u5728\u8150\u8680\u73af\u5883\u4e2d\u5177\u6709\u7a33\u5b9a\u7684\u5316\u5b66\u6027\u8d28\u3002\u4ece\u56fe 10c \u7ed3\u679c\u53ef\u77e5\uff0cS \u7684\u5206\u5e03\u4e0eAl \u5206\u5e03\u91cd\u53e0\uff0c\u56e0\u6b64\u53ef\u77e5 Na7Al6Si6O24S3\u662f Al \u53ca\u5176\u8868\u9762\u5305\u8986\u7684 SiO2\uff0cNa2SO4 \u5728\u8150\u8680\u73af\u5883\u4e0b\u5171\u540c\u4f5c\u7528\u751f\u6210\u7684\u8150\u8680\u4ea7\u7269\u3002\u7531\u4e8e Al \u7684 PBR&gt;1\uff0c\u6240\u4ee5\u7247\u72b6 Al \u586b\u6599\u7684\u6c27\u5316\u4f1a\u5f15\u8d77\u5982\u56fe 10a \u6240\u793a\u7684\u8868\u9762\u81f4\u5bc6\u6027\u63d0\u5347\uff0c\u968f\u540e\u5728\u8150\u8680\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u751f\u6210 Na7Al6Si6O24S3\uff0c\u65b0\u76f8 Na7Al6Si6O24S3 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