{"id":8521,"date":"2023-08-13T08:02:02","date_gmt":"2023-08-13T00:02:02","guid":{"rendered":"https:\/\/www.ztuzx.com\/?p=8521"},"modified":"2023-08-13T08:02:02","modified_gmt":"2023-08-13T00:02:02","slug":"tba%e7%8e%af%e6%b0%a7%e6%a0%91%e8%84%82%e8%b6%85%e8%96%84%e8%86%a8%e8%83%80%e5%9e%8b%e9%92%a2%e7%bb%93%e6%9e%84%e9%98%b2%e7%81%ab%e6%b6%82%e6%96%99%e7%9a%84%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"https:\/\/www.ztuzx.com\/?p=8521","title":{"rendered":"TBA\u73af\u6c27\u6811\u8102\u8d85\u8584\u81a8\u80c0\u578b\u94a2\u7ed3\u6784\u9632\u706b\u6d82\u6599\u7684\u7814\u7a76"},"content":{"rendered":"<p>\u7b2c 37 \u5377\u7b2c 3 \u671f 2007 \u5e74 3 \u6708  \u6d82 \u6599 \u5de5 \u4e1a PA INT \uff06 COA TI NG S IND UST R Y  V o1\uff0e 37 No\uff0e 3 Mat-\uff0e 20o7 TBA <a href='https:\/\/www.ztuzx.com\/?p=8271' title='\u73af\u6c27' target='_blank' rel=\"noopener\">\u73af\u6c27<\/a>\u6811\u8102\u8d85\u8584<a href='https:\/\/www.ztuzx.com\/?p=7726' title='\u81a8\u80c0' target='_blank' rel=\"noopener\">\u81a8\u80c0<\/a><a href='https:\/\/www.ztuzx.com\/?p=7740' title='\u578b\u94a2' target='_blank' rel=\"noopener\">\u578b\u94a2<\/a>\u7ed3\u6784<a href='https:\/\/www.ztuzx.com\/?p=8125' title='\u9632\u706b' target='_blank' rel=\"noopener\">\u9632\u706b<\/a><a href='https:\/\/www.ztuzx.com' target='_blank' rel=\"noopener\">\u6d82\u6599<\/a>\u7684\u7814\u7a76 \u6768\u4fdd\u5e73 \uff0c \u5468\u5e94\u840d \uff0c \u90ed\u519b\u7ea2 \uff0c\u9a6c \u52c7<strong>\u73af\u6c27\u9632\u706b<a href='https:\/\/www.ztuzx.com\/?p=8503' title='\u6d82\u6599' target='_blank' rel=\"noopener\">\u6d82\u6599<\/a><\/strong><a href='https:\/\/www.ztuzx.com\/'>\u6d82\u6599\u54c1\u724c\u7f51<\/a>\uff0c \u80e1\u957f\u9752 \uff0c \u5d14\u9526\u5cf0 (1\uff0e\u5170\u5dde\u7406\u5de5\u5927\u5b66\u77f3\u6cb9\u5316\u5de5\u5b66\u9662\uff0c \u5170\u5dde730050\uff1b 2\uff0e\u957f\u5e86\u7cbe\u7ec6\u5316\u5de5\u6709\u9650\u516c\u53f8\uff0c \u94f6\u5ddd750000) \u6458\u8981 \uff1a \u91c7\u7528\u53cc\u915a A ( BPA) \u5728\u9178\u6027\u4ecb\u8d28\u4e2d\uff0c \u4ee5\u4e59\u9187\u4e3a\u6eb6\u5242\uff0c \u4e0e NaBr\u3001 KBrO\uff0c \u5728\u8fc7\u6c27\u5316\u6c22\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\u53d1\u751f\u6eb4\u4ee3\u53cd\u5e94\uff0c  \u751f\u6210\u56db\u6eb4\u53cc\u915a A(TBA ) \uff1b TBA \u4e0e\u73af\u6c27\u6c2f\u4e19\u70f7(EHC)\u5728\u6c22\u6c27\u5316\u94a0\u6eb6\u6db2\u7684\u4f5c\u7528\u4e0b \uff0c \u901a\u8fc7\u9010\u6b65\u805a\u5408\u5f97\u5230 TBA \u578b\u73af\u6c27\u6811\u8102 \uff1b \u4ee5 TBA \u73af\u6c27\u6811\u8102\u4e3a\u6210\u819c\u7269\u8d28\u4e0e\u805a\u78f7\u9178\u94f5\u3001 \u4e09\u805a\u6c30\u80fa\u3001 \u5b63\u620a\u56db\u9187\u3001 \u4e09\u6c27\u5316\u4e8c\u9511\u3001 \u6c2f\u5316\u77f3\u814a \u3001 \u6c22\u6c27\u5316\u94dd\u3001 \u787c\u9178\u950c\u590d\u914d\u5f97\u5230 TBA \u578b \u73af\u6c27\u6811\u8102\u8d85\u8584\u81a8\u80c0\u578b\u94a2\u7ed3\u6784\u9632\u706b\u6d82\u6599 A \u7ec4\u5206\uff0c \u4ee5\u56fa\u5316\u5242\u805a\u9170\u80fa 300 \u4e3a B \u7ec4\u5206\uff0c m( A ) \uff1a m( B) \u4e3a 1\uff1a 1\u590d\u914d\u5f97\u5230\u5e38\u6e29\u56fa\u5316 \u578b\u53cc\u7ec4\u5206TBA \u73af\u6c27\u6811\u8102\u8d85\u8584\u81a8\u80c0\u578b\u94a2\u7ed3\u6784\u9632\u706b\u6d82\u6599\u3002<\/p>\n<p>  \u5173\u952e\u8bcd \uff1a \u56db\u6eb4\u53cc\u915a A (TBA) \uff1b TBA \u73af\u6c27\u6811\u8102\uff1b \u8d85\u8584\u81a8\u80c0\uff1b \u9632\u706b\u6d82\u6599 \u4e2d\u56fe\u5206\u7c7b\u53f7\uff1a TQ 637\uff0e 8 \u6587\u732e\u6807\u8bc6\u7801\uff1a A \u6587\u7ae0\u7f16\u53f7\uff1a 0253 \u2014 4312(2007)03 \u2014 0017 \u201405 T he Sy nthesis of T B A  E pox y R esin B ased Sup er \u2014 \u2014 thin In tu m escen t F ir e \u2014 \u2014 R etar d an t C oatings for Steel Str uctur e Y ang Baoping \uff0c Zhou Y ingping \uff0c Guo J unhong \uff0c Ma Y ong \uff0c Hu C hangqing \uff0c Cui J infeng ( 1\uff0eCollege o f Petrochemistry Engineedng\uff0c Lanzhou University o f Science and Technology \uff0c Lan zhou 730050\uff0cChina \uff1b 2 Ltd o f Chanqing Precision Chemi stry \uff0cYinchuan\uff0c Ningxia 750000\uff0c China) Abstract\uff1a The tetrabromobisphenol A ( TBA ) was prepared by use of bisphenol A ( BPA ) \uff0csodium bro\u2014  mide( NaBr) and potassium bromate( KBrO3) in an acid medium\uff0c ethanol as solvent\uff0c at the presence of hy\u2014  drogen peroxide\uff0e Under the c atalysis of sodium hydroxide solution \uff0cT BA epoxy resin was p repared by step\u2014  wise polymer i zation by use of tetrabromobisphenol A ( TBA ) and epichlorohydrin( E CH ) \uff0eAnd then compo\u2014  nent A of  TB A epoxy resin based su per \u2014 \u2014 thin intu mescen t struc tu ral f i re \u2014 \u2014 retardant c oatin gs Wa s  formulated by u se of T BA epoxy resin as f i lm \u2014 for m ing mater i al \uff0cmixed with ammonium polyphosphate \uff0cmelamine \uff0c  pentaerythr i tol \uff0cantimonous oxide \uff0cchloroparaff i n \uff0caluminum hydroxide and zinc borate\uff0eComponent B was cur i ng agent polyamide 300 \uff0eFinally \uff0c component A and B was mixed at the rato of 1\uff1a 1( m\uff0f m) to give the tide f i re \u2014retard ant coatings\uff0e  K ey Words\uff1a tetrabromobisphenol A ( TBA ) \uff1b TBA epoxy resin\uff1b super \u2014thin intumescent\uff1b f i re \u2014retardant c oa ting s 0\u5f15 \u8a00 \u56db\u6eb4\u53cc\u915a A( TBA )\u73af\u6c27\u6811\u8102\u662f\u4ee5\u56db\u6eb4\u53cc\u915a A \u66ff\u4ee3\u53cc\u915a A \u751f\u4ea7\u7684\u6eb4\u5316\u73af\u6c27\u6811\u8102 \uff0c \u53ef\u5e7f\u6cdb\u5e94\u7528\u4e8e\u963b\u71c3\u6d82\u6599\u3001 \u963b\u71c3\u5c42\u538b\u6750 \u6599\u7b49\u9886\u57df \uff0c \u56db\u6eb4\u53cc\u915a A \u73af\u6c27\u6811\u8102\u5e94\u7528\u4e8e\u9632\u706b\u6d82\u6599\u5177\u6709\u8bb8\u591a\u4f18 \u826f\u7684\u6027\u80fd J \uff1a ( 1) \u65e0\u6eb4\u6790\u51fa\uff0c \u957f\u6548\u9632\u706b\uff1b (2) \u70ed\u7a33\u5b9a\u6027\u597d\uff0c \u5206\u89e3 \u6e29\u5ea6\u9ad8\u4e8e300 o C \uff1b (3)\u4e0e\u57fa\u6750\u7684\u9644\u7740\u826f\u597d\uff1b (4) \u9632\u8150\u6027\u5f3a\uff1b (5) \u4ef7\u683c\u9002\u4e2d\uff1b (6) \u6bd2\u6027\u8f83\u5c0f\u3002<\/p>\n<p>\u91c7\u7528\u53cc\u915a A ( BPA ) \u5728\u9178\u6027\u4ecb\u8d28\u4e2d\uff0c  \u4ee5\u4e59\u9187\u4e3a\u6eb6\u5242\uff0c\u4e0e NaBr\u3001 KBrO<strong>\u73af\u6c27\u9632\u706b\u6d82\u6599<\/strong>\uff0c \u5728\u8fc7\u6c27\u5316\u6c22\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\u53d1\u751f \u6eb4\u4ee3\u53cd\u5e94\uff0c \u751f\u6210\u56db\u6eb4\u53cc\u915a A ( TBA ) \uff1b TBA \u4e0e\u73af\u6c27\u6c2f\u4e19\u70f7( EHC) \u5728\u6c22\u6c27\u5316\u94a0\u6eb6\u6db2\u7684\u4f5c\u7528\u4e0b\uff0c \u901a\u8fc7\u9010\u6b65\u805a\u5408\u5f97\u5230 TBA \u578b\u73af\u6c27\u6811 \u8102 \uff1b \u4ee5\u56db\u6eb4\u53cc\u915a A \u73af\u6c27\u6811\u8102\u4e3a\u6210\u819c\u7269\u8d28\u4e0e\u805a\u78f7\u9178\u94f5\u3001 \u4e09\u805a\u6c30 \u80fa\u3001 \u5b63\u620a\u56db\u9187\u3001 \u4e09\u6c27\u5316\u4e8c\u9511 \u3001 \u6c2f\u5316\u77f3\u814a\u3001 \u6c22\u6c27\u5316\u94dd \u3001 \u787c\u9178\u950c\u590d\u914d \u5f97\u5230TBA \u578b\u73af\u6c27\u6811\u8102\u8d85\u8584\u81a8\u80c0\u578b\u94a2\u7ed3\u6784\u9632\u706b\u6d82\u6599 A \u7ec4\u5206\uff0c \u4ee5 \u56fa\u5316\u5242\u805a\u9170\u80fa 300 \u4e3a B \u7ec4\u5206\uff0c A \u7ec4\u5206\u4e0e B \u7ec4\u5206\u6309 m( A ) \uff1a m ( B ) = 1\uff1a 1\u590d\u914d\u5f97\u5230\u5e38\u6e29\u56fa\u5316\u578b\u53cc\u7ec4\u5206 TBA \u73af\u6c27\u6811\u8102\u8d85\u8584\u81a8 \u80c0\u578b\u94a2\u7ed3\u6784\u9632\u706b\u6d82\u6599\u3002\u8be5\u9632\u706b\u6d82\u6599\u53d1\u6ce1\u6548\u679c\u597d \u3001 \u70ad\u5316\u7269\u751f\u6210 \u91cf\u5927\u3001 \u53d1\u70df\u5c11\u3001 \u6d82\u5c42\u9644\u7740\u529b\u5f3a \u3001 \u8010\u9178\u78b1\u6027\u597d\u3001 \u9632\u8150\u6027\u80fd\u4f18\u3002  l  \u5b9e\u9a8c\u7814 \u7a76 1\uff0e 1\u5b9e\u9a8c\u8bd5 \u5242 \u53cc\u915a A (BPA ) \uff1a \u5206\u6790\u7eaf\uff0c \u5929\u6d25\u5e02\u6cb3\u4e1c\u533a\u7ea2\u5ca9\u8bd5\u5242\u5382\uff1b 95\uff05 \u4f5c\u8005\u7b80\u4ecb\uff1a \u6768\u4fdd\u5e73( 1968\u4e00) \uff0c \u7537\uff0c \u7855\u58eb\uff0c \u526f\u6559\u6388\uff0c \u7855\u58eb\u751f\u5bfc\u5e08\uff0c \u4e3b\u8981\u4ece\u4e8b\u6d82\u6599\u3001 \u6cb9\u58a8\u65b9\u9762\u7684\u7814\u7a76\u4e0e\u6559\u5b66\u3002  \u7ef4\u666e\u8d44\u8baf<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u73af\u6c27\u6811\u8102\u8d85\u8584\u81a8\u80c0\u578b\u94a2\u7ed3\u6784\u9632\u706b\u6d82\u6599\u3002\u6bd2\u6027\u8f83\u5c0f\u3002\u80c0\u578b\u94a2\u7ed3\u6784\u9632\u706b\u6d82\u6599\u3002\u9632\u8150\u6027\u80fd\u4f18\u3002\u6cb9\u58a8\u65b9\u9762\u7684\u7814\u7a76\u4e0e\u6559\u5b66\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[20],"tags":[166,122,272,308,165],"class_list":["post-8521","post","type-post","status-publish","format-standard","hentry","category-bk","tag-166","tag-122","tag-272","tag-308","tag-165"],"_links":{"self":[{"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=\/wp\/v2\/posts\/8521","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=8521"}],"version-history":[{"count":0,"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=\/wp\/v2\/posts\/8521\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=8521"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=8521"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.ztuzx.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=8521"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}